资源类型

期刊论文 1856

会议视频 36

会议信息 2

会议专题 1

年份

2024 1

2023 85

2022 143

2021 138

2020 97

2019 135

2018 105

2017 112

2016 81

2015 102

2014 100

2013 78

2012 86

2011 83

2010 96

2009 66

2008 77

2007 96

2006 37

2005 28

展开 ︾

关键词

风险分析 9

能源 8

数值模拟 6

仿真技术 5

人工智能 4

分析 4

可持续发展 4

增材制造 4

对策 4

建模 4

影响因素 4

隧道 4

ANSYS 3

COVID-19 3

仿真 3

农业科学 3

抗击疫情 3

数值分析 3

智能制造 3

展开 ︾

检索范围：

排序： 展示方式：

Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

《环境科学与工程前沿（英文）》 2019年 第13卷 第5期 doi: 10.1007/s11783-019-1152-1

摘要： The wastewater from industrial area was treated by EC via Fe and Al electrodes. Cu, Ni, Cr and Zn were highly removed at the first minutes, simultaneously. Pseudo-2nd-order was found to be more suitable for kinetics. Adsorption capacities based on kinetic modeling were observed as Cr>Cu>Ni>Zn. The chemical cost in the case of pH adjustment after EC was less as 3.83 $/m3. It is known that wastewater produced by the metal-plating industry contains several heavy metals, which are acidic in nature and therefore toxic for the environment and for living creatures. In particular, heavy metals enter the food chain and accumulate in vital organs and cause serious illness. The precipitation of these metals is mostly achieved by pH adjustment, but as an alternative to this method, the electrocoagulation process has investigated in this study using iron and aluminum electrodes. The effects of the pH adjustment on removal before and after the electrocoagulation process were investigated, and cost analyses were also compared. It was observed that a high proportion of removal was obtained during the first minutes of the electrocoagulation process; thus, the current density did not have a great effect. In addition, the pH adjustment after the electrocoagulation process using iron electrodes, which are 10% more effective than aluminum electrodes, was found to be much more efficient than before the electrocoagulation process. In the process where kinetic modeling was applied, it was observed that the heavy metal removal mechanism was not solely due to the collapse of heavy metals at high pH values, and with this modeling, it was seen that this mechanism involved adsorption by iron and aluminum hydroxides formed during the electrocoagulation process. When comparing the ability of heavy metals to be adsorbed, the sequence was observed to be Cr>Cu>Ni>Zn, respectively.

关键词： Electrochemical treatment     Heavy metals     Kinetic modeling     Pseudo first order kinetic     Pseudo second order kinetic    

HTML PDF 收藏

Reduced kinetic mechanism of -heptane oxidation in modeling polycyclic aromatic hydrocarbon formation

ZHONG Beijing, XI Jun

《能源前沿（英文）》 2008年 第2卷 第3期   页码 326-332 doi: 10.1007/s11708-008-0047-9

摘要： A reduced mechanism, which could couple with the multidimensional computational fluid dynamics code for quantitative description of a reacting flow, was developed for chemical kinetic modeling of polycyclic aromatic hydrocarbon formation in an opposed-flow diffusion flame. The complete kinetic mechanism, which comprises 572 reactions and 108 species, was reduced to a simplified mechanism that includes only 83 reactions and 56 species through sensitivity analysis. The results computed via this reduced mechanism are nearly indistinguishable from those via the detailed mechanism, which demonstrate that the model based on this reduced mechanism can properly describe -heptane oxidation chemistry and quantitatively predict polycyclic aromatic hydrocarbon (such as benzene, naphthalene, phenanthrene and pyrene) formation in opposed-flow diffusion flames.

关键词： phenanthrene     multidimensional computational     sensitivity analysis     polycyclic     mechanism    

HTML PDF 收藏

Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101

Ehsan Rahmani, Mohammad Rahmani

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 1100-1111 doi: 10.1007/s11705-019-1891-3

摘要： A solvothermal method was used to synthesize MIL-101(Fe) and MIL-88(Fe), which were used for alkylation of benzene. The synthesized catalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, dynamic light scattering, and BET techniques. Metal-organic frameworks (MOFs) were modeled to investigate the catalytic performance and existence of mass transfer limitations. Calculated effectiveness factors revealed absence of internal and external mass transfer. Sensitivity analysis revealed best operating conditions over MIL-101 at 120°C and 5 bar and over MIL-88 at 142°C and 9 bar.

关键词： MOFs     alkylation     ethylbenzene     catalysts pellet model     kinetic model     sensitivity analysis    

HTML PDF 收藏

Kinetic study of the methanol to olefin process on a SAPO-34 catalyst

Mehdi SEDIGHI,Kamyar KEYVANLOO

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 306-311 doi: 10.1007/s11705-014-1440-z

摘要： In this paper, a new kinetic model for methanol to olefin process over SAPO-34 catalyst was developed using elementary step level. The kinetic model fits well to the experimental data obtained in a fixed bed reactor. Using this kinetic model, the effect of the most important operating conditions such as temperature, pressure and methanol space-time on the product distribution has been examined. It is shown that the temperature ranges between 400 °C and 450 °C is appropriate for propene production while the medium temperature (450 °C) is favorable for total olefin yield which is equal to 33%. Increasing the reactor pressure decreases the ethylene yield, while medium pressure is favorable for the propylene yield. The result shows that the ethylene and propylene and consequently the yield of total olefins increase to approximately 35% with decreasing the molar ratio of inlet water to methanol.

关键词： methanol to olefin     SAPO-34     kinetic modeling     elementary step    

HTML PDF 收藏

photoreduction process in a laboratory-scale photoreactor by computational fluid dynamic and reaction kineticmodeling

《化学科学与工程前沿（英文）》 2022年 第16卷 第7期   页码 1149-1163 doi: 10.1007/s11705-021-2096-0

摘要： The production of solar fuels via the photoreduction of carbon dioxide to methane by titanium oxide is a promising process to control greenhouse gas emissions and provide alternative renewable fuels. Although several reaction mechanisms have been proposed, the detailed steps are still ambiguous, and the limiting factors are not well defined. To improve our understanding of the mechanisms of carbon dioxide photoreduction, a multiphysics model was developed using COMSOL. The novelty of this work is the computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kinetic model, which was built based on three-steps, namely gas adsorption, surface reactions and desorption, while the ultraviolet light intensity distribution was simulated by the Gaussian distribution model and Beer-Lambert model. The carbon dioxide photoreduction process conducted in a laboratory-scale reactor under different carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic model. It was found that the simulation results for methane, carbon monoxide and hydrogen yield match the experiments in the concentration range of 10−4 mol·m–3 at the low carbon dioxide and water moisture partial pressure. Finally, the factors of adsorption site concentration, adsorption equilibrium constant, ultraviolet light intensity and temperature were evaluated.

关键词： carbon dioxide photoreduction     computational fluid dynamic simulation     kinetic model     Langmuir adsorption    

HTML PDF 收藏

Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

《能源前沿（英文）》 2015年 第9卷 第2期   页码 125-133 doi: 10.1007/s11708-015-0346-x

摘要： The thermal behavior of combustion in air atmosphere were investigated by performing experiments on STA PT1600 Thermal Analyzer at heating rates of 10°C/min, 40°C/min and 70°C/min and range of temperatures from room temperature to 1200°C. The kinetic parameters were evaluated by using Kissinger and Ozawa methods. The result showed that combustion occurred in five stages. Started with initial devolatilization, the main thermal decomposition and combustion process, transition stage, the combustion of char and the last stage was the slow burning reaction of residual char. In line with increasing heating rate, the mass loss rate increased as well, but it delayed the thermal decomposition processes toward higher temperatures. The average activation energy at the main thermal decomposition stage and the stage of char combustion were approximately 251 kJ/mol and 178 kJ/mol, respectively.

关键词： Nannochloropsis oculata     combustion     kinetic parameters     air atmosphere     thermogravimetric    

HTML PDF 收藏

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

《能源前沿（英文）》 2022年 第16卷 第2期   页码 263-276 doi: 10.1007/s11708-021-0791-7

摘要： The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas     laminar flame speed     kinetic model     sensitivity analysis     pathway analysis    

HTML PDF 收藏

ALKALINE PRETREATMENT AND AIR MIXING FOR IMPROVEMENT OF METHANE PRODUCTION FROM ANAEROBIC CO-DIGESTION OF POULTRY LITTER WITH WHEAT STRAW

《农业科学与工程前沿（英文）》 2023年 第10卷 第3期   页码 424-436 doi: 10.15302/J-FASE-2023506

摘要：

● Integration of alkaline pretreatment and air mixing for co-digestion was validated.

关键词： sodium hydroxide     air injection     cumulative methane yield     kinetic modeling analysis     digestate    

HTML PDF 收藏

Kinetic energy based model assessment and sensitivity analysis of vortex induced vibration of segmental

Nazim Abdul NARIMAN

《结构与土木工程前沿（英文）》 2017年 第11卷 第4期   页码 480-501 doi: 10.1007/s11709-017-0435-5

摘要： In this paper, semi 3D models for segmental Bridge decks are created in ABAQUS CFD program with the support of MATLAB codes to simulate and analyze vortex shedding generated due to wind excitation through considering the stationary position of the deck. Three parameters (wind speed, deck streamlined length and dynamic viscosity of the air) are dedicated to study their effects on the kinetic energy of the system in addition to the shapes and patterns of the vortices. Two benchmarks from the literature Von Karman and Dyrbye and Hansen are considered to validate the vortex shedding aspects for the CFD models. Good agreement between the results of the benchmarks and the semi 3D models has been detected. Latin hypercube experimental method is dedicated to generate the surrogate models for the kinetic energy of the system and the lift forces. Variance based sensitivity analysis is utilized to calculate the main sensitivity indices and the interaction orders for all the three parameters. The kinetic energy approach performed very well in revealing the rational effects and the roles of each parameter in the generation of vortex shedding and predicting vortex induced vibration of the deck.

关键词： vortex induced vibration     reynolds number     kinetic energy     vorticity     latin hypercube sampling    

HTML PDF 收藏

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

《环境科学与工程前沿（英文）》 2022年 第16卷 第10期 doi: 10.1007/s11783-022-1570-3

摘要：

● Collaborative treatment of plastics and OS was established to improve oil quality.

关键词： Oily sludge     Pyrolysis     Polyethylene     H/Ceff ratio     Oil quality    

HTML PDF 收藏

Comparison and modeling of two biofilm processes applied to decentralized wastewater treatment

Guanglei QIU, Yonghui SONG, Peng YUAN, Liancheng XIANG, Jianfeng PENG, Ping ZENG,

《环境科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 412-420 doi: 10.1007/s11783-009-0141-1

摘要： In order to control water pollution in the rapidly urbanizing South China area, biological contact oxidation (BCO) process and biological aerated filter (BAF) process were applied in a pilot-scale experiment for decentralized wastewater treatment. An investigation to find the optimal parameters of the two biofilm systems was conducted on hydraulic loading, organic loading, and aeration rate. The results indicated that the water reuse criteria required a maximum hydraulic and organic loading of 30.0 m/(m·d) and 4.0 kg COD/(m·d), respectively, as well as a minimum effluent DO of 4.0 mg/L. The utilization of a new media allowed BAF to perform better than BCO. The kinetic description of the COD removal process for BAF and BCO are Yang ZHANG,Zifu LI,Ibrahim B MAHMOOD. [J]. Front. Environ. Sci. Eng., 2014, 8(6): 825-834.Daijun ZHANG, Cui BAI, Ting TANG, Qing YANG. [J]. Front Envir Sci Eng Chin, 2011, 5(2): 291-297.Deming ZHAO, Jie CHENG, Michael R. HOFFMANN. [J]. Front Envir Sci Eng Chin, 2011, 5(1): 57-64.Bo WANG, Wei WAN, Jianlong WANG, . [J]. Front.Environ.Sci.Eng., 2009, 3(4): 380-386. Junxiong LIN , Lan WANG , . [J]. Front.Environ.Sci.Eng., 2009, 3(3): 320-324.Lu LI, Shuguang XIE, Hui ZHANG, Donghui WEN. [J]. Front Envir Sci Eng Chin, 2009, 3(1): 38-47.

关键词： biological contact oxidation     biological aerated filter     decentralized wastewater treatment     kinetic model    

HTML PDF 收藏

Kinetic analysis of anaerobic phosphorus release during biological phosphorus removal process

DOU Junfeng, LIU Xiang, LUO Guyuan

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 233-239 doi: 10.1007/s11783-007-0040-2

摘要： Enhanced biological phosphorus removal (EBPR) is a commonly used and sustainable method for phosphorus removal from wastewater. Poly-β-hydroxybutyrate (PHB), polyphosphate, and glycogen are three kinds of intracellular storage polymers in phosphorus accumulation organisms. The variation of these polymers under different conditions has an apparent influence on anaerobic phosphorus release, which is very important for controlling the performance of EBPR. To obtain the mechanism and kinetic character of anaerobic phosphorus release, a series of batch experiments were performed using the excessively aerated sludge from the aerobic unit of the biological phosphorus removal system in this study. The results showed that the volatile suspended solid (VSS) had an increasing trend, while the mixed liquid suspended sludge (MLSS) and ashes were reduced during the anaerobic phosphorus release process. The interruption of anaerobic HAc-uptake and phosphorus-release occurs when the glycogen in the phosphorus-accumulating-organisms is exhausted. Under the condition of lower initial HAc-COD, HAc became the limiting factor after some time for anaerobic HAc uptake. Under the condition of higher initial HAc-COD, HAc uptake was stopped because of the depletion of glycogen in the microorganisms. The mean ratio of ΔρP/Δρ, Δρ/ΔρPHB, ΔρP/ΔCOD, and ΔρPHB/ΔCOD was 0.48, 0.50, 0.44, and 0.92, respectively, which was nearly the same as the theoretical value. The calibrated kinetic parameters of the HAc-uptake and phosphorus-release model were evaluated as follows: Q was 164 mg/(g °h), Q was 69.9 mg/(g °h), K was 0.005, and KCOD was 3 mg/L. An apparently linear correlation was observed between the ratio of ΔρP/ΔCOD and pH of the solution, and the equation between them was obtained in this study.

关键词： interruption     process     ΔρP/Δρ     Enhanced biological     Poly-β-hydroxybutyrate    

HTML PDF 收藏

Integrating storm surge modeling with traffic data analysis to evaluate the effectiveness of hurricane

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1301-1316 doi: 10.1007/s11709-021-0765-1

摘要： An integrated storm surge modeling and traffic analysis were conducted in this study to assess the effectiveness of hurricane evacuations through a case study of Hurricane Irma. The Category 5 hurricane in 2017 caused a record evacuation with an estimated 6.8 million people relocating statewide in Florida. The Advanced Circulation (ADCIRC) model was applied to simulate storm tides during the hurricane event. Model validations indicated that simulated pressures, winds, and storm surge compared well with observations. Model simulated storm tides and winds were used to estimate the area affected by Hurricane Irma. Results showed that the storm surge and strong wind mainly affected coastal counties in south-west Florida. Only moderate storm tides (maximum about 2.5 m) and maximum wind speed about 115 mph were shown in both model simulations and Federal Emergency Management Agency (FEMA) post-hurricane assessment near the area of hurricane landfall. Storm surges did not rise to the 100-year flood elevation level. The maximum wind was much below the design wind speed of 150–170 mph (Category 5) as defined in Florida Building Code (FBC) for south Florida coastal areas. Compared with the total population of about 2.25 million in the six coastal counties affected by storm surge and Category 1–3 wind, the statewide evacuation of approximately 6.8 million people was found to be an over-evacuation due mainly to the uncertainty of hurricane path, which shifted from south-east to south-west Florida. The uncertainty of hurricane tracks made it difficult to predict the appropriate storm surge inundation zone for evacuation. Traffic data were used to analyze the evacuation traffic patterns. In south-east Florida, evacuation traffic started 4 days before the hurricane’s arrival. However, the hurricane path shifted and eventually landed in south-west Florida, which caused a high level of evacuation traffic in south-west Florida. Over-evacuation caused Evacuation Traffic Index (ETI) to increase to 200% above normal conditions in some sections of highways, which reduced the effectiveness of evacuation. Results from this study show that evacuation efficiency can be improved in the future by more accurate hurricane forecasting, better public awareness of real-time storm surge and wind as well as integrated storm surge and evacuation modeling for quick response to the uncertainty of hurricane forecasting.

关键词： storm surge modeling     traffic     evacuation     Hurricane Irma    

HTML PDF 收藏

Factor analysis for the statistical modeling of earthquake-induced landslides

Jeng-Wen LIN, Meng-Hsun HSIEH, Yu-Jen LI

《结构与土木工程前沿（英文）》 2020年 第14卷 第1期   页码 123-126 doi: 10.1007/s11709-019-0582-y

摘要： Earthquake-induced landslides are difficult to assess and predict owing to the inherent unpredictability of earthquakes. In most existing studies, the landslide potential is statistically assessed by collecting and analyzing the data of historical landslide events and earthquake observation records. Unlike rainfall-induced landslides, earthquake-induced landslides cannot be predicted in advance using real-time monitoring systems, and the development of the models for these landslides should instead depend on early earthquake warnings and estimations. Hence, in this study, factor analysis was performed and the frequency distribution method was employed to investigate the potential risk of the landslides caused by earthquakes. Factors such as the slope gradient, lithology (geology), aspect, and elevation were selected and classified as influential factors to facilitate the construction of a landslide database for the area of study.

关键词： earthquake     factor analysis     slope landslides     statistical modeling    

HTML PDF 收藏

On the added value of multi-scale modeling of concrete

《结构与土木工程前沿（英文）》 2022年 第16卷 第1期   页码 1-23 doi: 10.1007/s11709-021-0790-0

摘要： This review of the added value of multi-scale modeling of concrete is based on three representative examples. The first one is concerned with the analysis of experimental data, taken from four high-dynamic tests. The structural nature of the high-dynamic strength increase can be explained by using a multi-scale model. It accounts for the microstructure of the specimens. The second example refers to multi-scale thermoelastic analysis of concrete pavements, subjected to solar heating. A sensitivity analysis with respect to the internal relative humidity (RH) of concrete has underlined the great importance of the RH for an assessment of the risk of microcracking of concrete. The third example deals with multi-scale structural analysis of a real-scale test of a segmental tunnel ring. It has turned out that multi-scale modeling of concrete enables more reliable predictions of crack opening displacements in tunnel segments than macroscopic models taken from codes of practice. Overall, it is concluded that multi-scale models have indeed a significant added value. However, its degree varies with these examples. In any case, it can be assessed by means of a comparison of the results from three sources, namely, multi-scale structural analysis, conventional structural analysis, and experiments.

关键词： experiments     multi-scale analysis     conventional structural analysis     concrete     reinforced concrete    

HTML PDF 收藏

标题 作者 时间 类型 操作

Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

期刊论文

Reduced kinetic mechanism of -heptane oxidation in modeling polycyclic aromatic hydrocarbon formation

ZHONG Beijing, XI Jun

期刊论文

Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101

Ehsan Rahmani, Mohammad Rahmani

期刊论文

Kinetic study of the methanol to olefin process on a SAPO-34 catalyst

Mehdi SEDIGHI,Kamyar KEYVANLOO

期刊论文

photoreduction process in a laboratory-scale photoreactor by computational fluid dynamic and reaction kineticmodeling

期刊论文

Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

期刊论文

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

期刊论文

ALKALINE PRETREATMENT AND AIR MIXING FOR IMPROVEMENT OF METHANE PRODUCTION FROM ANAEROBIC CO-DIGESTION OF POULTRY LITTER WITH WHEAT STRAW

期刊论文

Kinetic energy based model assessment and sensitivity analysis of vortex induced vibration of segmental

Nazim Abdul NARIMAN

期刊论文

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

期刊论文

Comparison and modeling of two biofilm processes applied to decentralized wastewater treatment

Guanglei QIU, Yonghui SONG, Peng YUAN, Liancheng XIANG, Jianfeng PENG, Ping ZENG,

期刊论文

Kinetic analysis of anaerobic phosphorus release during biological phosphorus removal process

DOU Junfeng, LIU Xiang, LUO Guyuan

期刊论文

Integrating storm surge modeling with traffic data analysis to evaluate the effectiveness of hurricane

期刊论文

Factor analysis for the statistical modeling of earthquake-induced landslides

Jeng-Wen LIN, Meng-Hsun HSIEH, Yu-Jen LI

期刊论文

On the added value of multi-scale modeling of concrete

期刊论文